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Marcos Alcocer

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Food x Immune system –

a daily battle usually with no winners









Marcos Alcocer



Nutritional Sciences

Sutton Bonington campus

University of Nottingham

United Kingdom

IAFP - Campinas 2008



How does food interacts with the IS?

Background

Is food allergy a problem?



Is the prevalence of food allergy increasing?



(What makes an allergen???)



Where does our work fit in this????

Other work

Protein microarray work

Questions







Are we tolerant to all food proteins ?



Are all food (plant) proteins allergenic ?



Which are the characteristics of a molecule that

are responsible for its allergenicity ?



Can we predict when a protein is allergenic ?

Background

The Gut is Bombarded by Foreign Antigens



•Eradication

•Containment

No Response

(Tolerance) • “Disease”



• Crosslinking of IgE by food Ag

• Activation of mucosal mast cells

• Release of inflammatory mediators

 Transepithelial fluid loss

 Smooth muscle contraction

Response

 Vomiting and diarrhoea

(Immune Activation)

 Anaphylaxis









mucosal barrier

Mast Cell / basophil degranulation









Video 2

The Th2 response

J ALLERGY CLIN IMMUNOL

VOLUME 121, NUMBER 2

NOVAK AND BIEBER

Is food allergy a problem?

Anaphylaxis Deaths 1992-98





uncertain, 4

peanut

nectarine, 1

walnut

banana, 1 nuts

peanut, 10

milk, 2 chickpea

seafood, 3 seafood



chickpea, 1 milk

walnut, 5

banana

nuts, 10 nectarine

uncertain









Pumphrey 2000

Is the prevalence of food allergy increasing?

Number of cases of anaphylaxis to food

products are increasing…









Gupta & Sheikh, BMJ,2003

Atopic march









Asthma

Incidence









Rhinitis





Eczema

Food allergy

0 1 2 4 8 16 32 64

Age (years)



Redrawn from Durham SR & Church MK, Allergy 2nd edition, 2001, Mosby

Prevalence of IgE mediated food allergy





1992 - USA – 950 cases/year or 0.0004%



1994 - 2% infants – cow’s milk allergy





1998 - USA – 10% of general population= atopic

Europe - 0.3 –7.5%

Europe - 10% atopic = food allergic



2005-7 – USA – 3.5-4% adults

6-8% young children and infants



2007/8– UK, comprehensive House of Lords report - ??????

Where does our work fit in this?

Food allergens work at Nottingham









Protein model system



In vitro DC-studies



Effect of Food matrix



HTP screening

Protein model system





Ber e 1: Brazil nut 2S albumin, well-known allergen, (45,000 tone/year)



SFA 8 : Sunflower 2S albumin, “weak” allergen, (26,852,000 tone/year)

What makes an allergen?





“allergenicity” ????









SFA 8 : Sunflower 2S Ber e 1: Brazil nut 2S albumin

albumin “weak” allergen well-known allergen

IOW67

IOW59

80 GJM 15 IOW52



Lambda (nm) vs Ber e 1 IOW46

60 Lambda (nm) vs SFA8

Lambda (nm) vs pGJM 13 IOW42

Lambda (nm) vs pGJM 10

Lambda (nm) vs pGJM 16 IOW38

40 Lambda (nm) vs pGJM 09

Lambda (nm) vs pGJM 12 IOW37

Lambda (nm) vs pGJM 15

[deg cm2 dmol-1









GJM 13

20

MANe

MANd

0 MANc

MANb

-20

MANa

GJM 12

ITAb

-40





“The major IgE structural epitope

ITAa

ITA06

recognised of Ber e 1 was mapped to a

-60

ITA05

200 210 220 230 240 250

single helix-loop-helix region.”

GJM 16

ITA04

(nm)

ITA03

ITA02

ITA01







GJM 10









GJM 09









SFA8









0.00 20.00 40.00 60.00 80.00 100.00 120.00

I Fluor. x100/I Fluor. Be r e 1

Journal of Molecular Biology, 343:759-769

Protein model system









-All the backbone assigned

EAEAQEECREQMQRQQMLSHCRMYMRQQMEESTYQTMPRRGMEPHMSECCEQLEGMDESCRCE

GLRMMMRMMQQKEMQPRGEQMRRMMRLAENIPSRCNLSPMRCPMGGSIAGF



-Multiple resonances for several residues “Labelled 13C/15N proteins have

been produced and purified. The NMR

3D structure in solution of Ber e 1 is

determined”

Journal of Biomolecular NMR, 32(4):336 (2005)

Food allergens work at Nottingham

“ Early decisions were taken by DC

and ability of Ber e 1 to induce a

Th2 response is depending on the

genetic background”

Protein model system

NON-ATOPIC ATOPIC

In vitro DC-studies

Ber e 1 SFA8 Ber e 1 SFA8





DC CD40 DC DC CD40 DC

ligation ligation



T IL-12 IL-12

IL-12 IL-12 no IL-12 T







Th1 Th1 Th2 Th1





ALLERGY

Food allergens work at Nottingham



1

Dia 0

m 8



Protein model system PC 6

A

rea 4

c.



In vitro DC-studies (m

2



m)

W RE RE REC R RE RE N



Effect of Food matrix

T C C com E C C M

ster tot plex C oth low S

oid al lipids ers mol

lipi wt

ds

NO IgE !!!







“Protein alone is unable to trigger

allergic response. A second natural

signal present in the seed needs to

be present ”

“The allergenic work at Nottingham

Food allergens protein is able to

bind and present natural lipids or

hydrophobic molecules ”









Lipid binding ??

Partial conclusions









Allergenicity of proteins are product of complex signals such as genetic

background, structure of the allergen and food matrix.





Certain cells of the immune system such as DC are the main orchestrators

of the allergic response

How do the non-immune compromised

(normal) population interacts with food?

Protein microarray







B B





G B

Fluorescence B









E

Wheat LTP

Trypsin inhibitor

Trypsin/Chym.inh.

Thyroglobulin





Protein microarray

rSoya 2S Alb1

Soya 2S Alb 3 w t

rSoya 2S Alb 3

Soya 11S

SFA8 w t

rSFA8

Protein A

Pichia extract

Pepstatin

Peanut 05

Peanut 03

Papain

rOV-20

Mouse IgE

lysozyme chicken

Lectin Soya

Lectin Hypogae

hu.sera albumin

human IgG1

human IgE

Gelatine

Concanavalin

Chicken albumin

Carb.anhydr.

Calreticulin w t IoW37 IgE

rCalreticulin IoW52 IgE

Brazilnut total IoW37 IgG4

Bovine albumin

IoW52 IgG4

Beta amylase

Ber e 1 w t

rBer e 1

Ara h 2

Apoferritin

Alc.dehydrog.



0 2000 4000 6000 8000

Fluorescence 532 nm

“All British diet array”









E

G







400 food ingredients “All British diet array”

1.500 “intact” protein groups x 4

Four lasers = IgE/M/A/G -> 20.000 data points/patient

Main applications:



• Specific IgE screening allergic subjects

• Specific IgE screening post-morten

• Specific Ig (A/G/M) screening:

Serum, Milk, saliva.

Vegetables Fruits Herbs and Spices

Alfalfa, Artichoke, Asparagus, Aubergine, Avocado, Baby Chard Leaf, Bamboo Apple, Apricot, Banana, Blackberry, Blackcurrant, Blueberry, Cherry, Arrowroot, Basil, Bay Leaves, Black Pepper, Camomile, Cardamom, Cayenne

Shoot, Beansprout, Beetroot, Bhindi, Borlotti Bean, Broad Bean, Broccoli, Brussels Clementine, Coconut (Desiccated), Coconut Milk, Currants, Dates, Fig, Pepper, Chilli Powder, Cinnamon, Cloves, Coriander (Ground), Cumin, Curry

Sprout, Butternut Squash, Cabbage, Caper, Carrot, Cauliflower, Celeriac, Celery, Gooseberry, Grape, Grapefruit (Red), Guava, Italian Kiwi, Italian Kiwi Leaves, Curry Powder, Custard Powder, Dill, Earl Grey, Fennel Seed, Fragrance

Chervil (Fresh), Chickpea (Cooked), Chilli (Green), Chilli (Red), Chinese Cabbage, (Hayward), Kiwi, Kiwi (Protein), Lemon, Lemon Rind, Lime, Lychee, spice, Garam Masala, Ginger (Ground), Juniper Berry, Lemongrass, Lime Leaves,

Chives (Fresh), Coriander Leaf, Courgette, Cress, Cucumber, Dal Chini, Fennel, Mandarin Peel, Mango, Melon, Nectarine, Orange, Orange Marmalade, Liquorice Root, Marjoram, Mint, Nutmeg, Oregano, Paprika, Parsley, Peppermint,

Ganna (Spain), Garlic, Gherkin, Leek, Lettuce, Lettuce (Lambs), Maize Babycorn, Papaya, Passion Fruit, Paw Paw, Peach, Pear, Physalis, Pineapple, Plum, Pimiento Pepper, Rosemary, Saffron, Sage, Tarragon, Tea Leaves, Thyme,

Mange Tout, Marrow, Mushroom, Mushroom (Oyster), Mushroom (Shitake), Okra, Pomegranate, Prune, Pumpkin, Raisins, Rambutant, Raspberry, Rhubarb, Turmeric.

Olive (Black), Olive (Green), Onion (Red), Onion (White), Pak Choi, Parsnip, Peas, Sharon Fruit, Strawberry, Sultanas, Tamarind (Dried), Tamarind (Fresh),

Pepper (Red), Potato, Radish, Rocket, Runner Bean, Seaweed, Shallot, Spinach, Tangerine, Watermelon.

Spring Onion, Swede, Sweetcorn, Texturised Vegetable protein, Tomato, Turnip,

Water Chestnut, Watercress.



Beans Nuts Cereals



Baked Bean, Black Bean, Black Canna (Chickpea), Black eyed Bean, Black Kidney Almond, Almond, Almond (Blanched), Barley Seed, Brazil Nut, Brazil Nut Basmati Rice, Bread (White), Corn, Corn Starch, Cornflour, Cous Cous, Egg Noodle,

Bean, Butter Bean, Cannalini Bean (Cooked), Chicory, Coffee Bean, Flageolet (Protein), Cashew, Chestnut, Hazelnut, Hazelnut (Organic), Lectin Flour (Chapatti), Lentil (Red), Oats, Pasta, Pearl Barley, Rice (Arborio), Rice

Bean, Green Mung Bean, Haricot Bean, Lectin (Soya), Lentil Yellow (Moog dal), (Peanut), Macadamia, Paleskin Nut, Peanut, Peanut (Blanched), Pecan, (Basmati), Rice (Red), Rye, Sago, Tapioca, Wheat, Wheat Flour, Wheat Germ,

Pinto Bean, Red Bean, Red Kidney Bean, Soya (Total Protein), Soya Bean, Soya Pine Kernel, Pine Nut Kernel, Pistachio, Rye Seed, Walnut, Walnut Wheat LTP.

Bean (UK Soy), Soya Flour, Soya Milk, Soya Milk (Extract), Soya Sprout, Split (Organic).

Chick pea (ChannaDal), Tofu (Extract).



Seeds Dairy Meat



Aniseed, Aniseed Star, Caraway Seeds, Celery Seed, Cocoa, Coriander Seed, Brie, Buttermilk, Cheddar, Cottage Cheese, Cow's Milk, Cow's Milk (Whey), Bacon, Beef, Beef Stock, Chicken, Chicken Liver, Duck, Gelatine, Ham, Kidney (Pig),

Fenugreek, Green Pepper Seeds, Hemp Seed, Linseed, Mustard (Black), Mustard Cream, Edam, Feta, Fromage frais, Goat's Milk, Greek Yogurt, Mozzarella, Lamb Liver, Pepperoni, Pig Liver, Pork, Sausage Casing, Smoked Bacon, Suet,

(Yellow), Mustard Seeds (Black), Pomegranate Seed, Poppy Seed, Rape Seed, Parmesan, Sour Cream, Stilton, Tofu (Paneer), Yogurt (Plain). Turkey, Venison.

Sesame, Sunflower Seed, White Pepper Seed.



Fish Drink and Sauce Others



Anchovy, Cod, Coley Fish, Herring, Kipper, Mackerel, Pilchards, Plaice, Salmon, Ale, Beer, Black Bean Sauce, Black Pepper Sauce, Cranberry Sauce, Baking Powder, Chocolate, Chocolate (Plain), Cream of Tartar, Glutamine (MSG),

Sardine, Smoked Haddock, Sprat, Trout, Tuna. Horseradish Sauce, Malt Vinegar, Marmite, Satay Sauce, Sherry, Soya Pichia, Rock Salt, Sugar (Brown), Sugar (Muscavado), Yeast (Dry).

Sauce, Vegetable Stock, Worcestershire Sauce.









Shellfish Eggs Inhaled Allergens



Cockles, Crab, Crab (Cooked), Mussels, Oyster, Oyster Sauce, Prawn, Scallop, Duck Egg, Duck Egg (White), Duck Egg (Yolk), Duck egg white, Egg Birch Pollen, Grass Pollen, Grass Pollen (Velvet), House dust mite, Nectar.

Squid. Albumin, Egg Ovalbumin, Hen Egg, Hen Egg (White), Hen Egg (Yolk).

“ Normal” population does produce

food specific antibodies in large

quantities.



IgA IgG









60000 60000





50000 50000

532 nm









594 nm

40000 40000

Fluorescence









Fluorescence

30000 30000



20000 20000

400 400

350 350

10000 300 10000 300









ts









ts

“ Some allergic people are

uc









uc

250 250









od

od

200 200

0 0









pr

150 pr 15 14 150



polyspecific, others mono specific.”

15 14









d

od

13 12 13 12









o

11 10 100 11 10 100









Fo

Fo



9 8 9 8

7 6 50 7 6 50

5 4 5 4

Patie 3 0 Patie 3 2 0

nts IgM 2 1 0 nts 1 0

IgE









“ Non allergic control patients also

60000

20000





produce low level of food specific

50000 18000

488 nm









16000

635 nm









IgE.”

40000

14000

Fluorescence









30000 12000

Fluorescence









10000

20000

400 8000

350 6000

10000 300 400

ts









350

uc









250 4000

od









300









cts

200

0

pr









2000 250









du

15 14 150

od









13 12 200









o

11 10 100 0









pr

Fo









9 8 15 14 150

7 6









od

50 13 12

5 4 11 10 100









Fo

Patie 3 2 0 9 8

nts 1 0 7 6 50

5 4

Patie 3 2 0

nts 1 0

Atopic produced less total IgG than

non-atopic.



Atopic Non-Atopic

* Significant Difference (P<0.002) *

* * * * * IgG

Adjusted Relative Scale









*Significant Difference (P<0.050) * *

* * *

IgE

* Significant Difference (P<0.004)

IgA

*

* * *

* Significant Difference (P<0.050)





IgM

*

Some food classes induce food

iry

h









r

h







ts









ce

at

es

ble





s/S it







s









s







ls







gs









s

he

u







ed









an









en

Fis



fis









ria

Nu

Me









Da

Fr









au

Eg

pic

eta









Ot

ell

Se









Be









rg

specific antibodies in large quantities.

Ce









/S



lle

Sh

eg









ink

dA

rb

t/V









Dr

He









ale

an

Pl









Inh

Array, preliminary data – Milk sample







9000



8000



7000



6000



5000





Fluorescence 4000



3000



2000



1000

S15

S13

0

S11

-1000 S9



Days

795









S7

822

1199

998

1299

517

1416

1079









S5

966

904

911

1030

1134

511









S3

1446

838

519

964

933

988

S1



1215

804



426

Samples (ID)



1114



488



1335

Protein microarray+ basophils????









E









G

Activation of RBL 703/21

 Light

microscope









 GenePix 4000B

scanner Fluorescent intensity (Measured using GenePix software





GPA IgE

491 592 295 344 695 472



E

G



27 47 94 6 5

Anti IgE

Grass pollen

IAFP - Campinas 2008





Our immune system “responds” to our daily load of food proteins



Allergenicity of proteins are product of complex signals such as genetic

background, structure of the allergen and food matrix.





Certain cells of the immune system such as DC are the main orchestrators

of the allergic response



Some food groups are referentially recognised by our immune system.





Novel high-throughput systems are allowing a comprehensive “fingerprinting”

of the immune response to food proteins

Acknowledgements





Zellulaere Allergologie

Forschungszentrum Borstel

Germany

Helmut Haas

Gabi Schramm

School of Pharmacy

University of Nottingham

United kingdom

Franco Falcone

Paul Ehrlich

Institute

Germany

Lothar Vogel

Stefan Vieth



University of Strathclyde

Syngenta Scotland

School of Biosciences

University of Nottingham William Harnett

BBSRC

Universite de Liege

School of Biology Belgium

University of Nottingham Alain Brans

D. Archer



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