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Calculation



Conversion of hartree to kJ/mol



1hartree= 2 625.5kJ/mol.1



(2625.5kJ / mol)

1. (75.6260hartree)  1.9857  105 kJ / mol OH

1hartree

(2625.5kJ / mol)

2. (74.9648hartree)  1.9682  105 kJ / mol O

1hartree

(2625.5kJ / mol)

3. (0.4998hartree)  1.3122  103 kJ / mol H

1hartree



Bond Energy with Conversion to kJ/mol



Literature value 464 kJ/mol



EEOH=EEO+EEH-BEOH

1.3122  10 3 kJ / mol  1.9682  10 5 kJ / mol  1.9857  10 5 kJ / mol

 437 .8kJ / mol

1



% Bond Energy to Electronic Energy



437.8kJ / mol

*100  .2204%

1.9857  105 kJ / mol







References:

1. Energy Conversion Table. http://mccammon.ucsd.edu/~dzhang/energy-unit-conv-table.html

(February, 2 2010)



2. Bond Energy. http://science.jrank.org/pages/984/Bond-Energy.html (February, 2 2010)



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