LABORATOIRE MSSMAT LISTE DES PRODUITS CHIMIQUES DISPONIBLES MARS 2009
BASES DE DONNEES A CONSULTER http://ecb.jrc.ec.europa.eu/esis/
http://www.chemblink.com/index.htm
http://www.cdc.gov/niosh/ipcsnfrn/nfrn0000.html#N
NAME CAS EINECS RISK CODE SAFETY DESCRIPTION
NOM CHIMIQUE N°CAS N°CE Indication de danger Conseils de prudences (S)
Nature des risques (R)
acétate d'uranyle 6159-44-0 T+,R,N R 26/28-33-51/53 20/21-45-61
acetic acid glacial /Acide 64-19-7 C; R35 R10 S 23-26-36/37/39-45
acétique 200-580-7
Acétone 67-64-1
200-662-2 F; R11 - Xi; R36 - R66 - R67 S16;S26;S9
acetonitrile 75-05-8 F; R11 - Xn; R20/21/22 - Xi; R36 S16;S36/37
alumine al2o3 1344-28-1 S24/25
C R34
aluminium chlorid 7446-70-0 231-208-1 S1/2 S7/8 S28 S45
Aluminium hydroxide /alumine 21645-51-2 244-492-7 Xi R36 S26;S36
Aluminium nitrate nonahydrate 7784-27-2 ------------ O;Xn R22;R36;R8 S17;S26
benzène 71-43-2 F; R11 - Carc. Cat. 1; R45 - Muta. Cat. 2; S 53 45
R46 - T; R48/23/24/25 - Xn; R65 - Xi;
R36/38
Butanol-1 71-36-3 Xn R10;R22;R37/38;R41;R67 S13;S26;S37/39;S46;S7/9
200-751-6
butanol-2 78-92-2 S 2 S7/9 S13 S24/25 Q26
201-158-5 R10 - Xi; R36/37 - R67 S46
Chloroacetic acid 79-11-8 607-003-00-1 T N R25-34-50 S: (1/2-)23-37-45-61
236-921-1 O ; Xi ; R 8-36/38
chromic nitrate 13548-38-4 S17;S26;S36
Cobalt II 200g 7440-48-4 027-001-00-9 Xn R: 42/43-53 S: 2-22-24-37-61
copper /Cuivre poudre 7440-50-8 F R11 S 11
231-159-6
Cupric nitrate trihydrate /cuivre ----------------
(Ii) nitrate 10031-43-3 --- Xi R : 22-36/38 S26;S37/39
Decane /n-décane 124-18-5 204-686-4 Xn R10;R65;R66 S16;S23;S62
Diaminodiphenyl sulfone 80-08-0 201-248-4 Xn; R22 S22
dichloromethane 75-09-2 Carc. Cat. 3; R40
Dimethyl sulfoxide 67-68-5 200-664-3 Xi R36/37/38 S26;S37/39
Dimethylformamide,ACS,99,8+°/° et 68-12-2 200-679-5 Repr. Cat. 2; R61 - Xn; R20/21 - Xi; R36 S45;S53
disodium disulphite / Sodium 7681-57-4 S 26-39 S2 S46
disulfite 231-673-0 Xn; R22 - Xi; R41 - R31
Dodecane/ n-docécane 112-40-3 203-967-9 N I R65;R66 S36;S60;S62
Ethanol 64-17-5 200-578-6 F; R11 S2 S7S16
ether monobutylique de l’éthylène 111-76-2 Xn R20/21/22 Xi; R36/38 S 24/25
glycol 203-905-0
Ethylenediamine 107-15-3 203-468-6 C R: 10-21/22-34-42/43 S23;S26;S36/37/39;S45
Fer chlorure 7785-94-3 Xn R22-38-41 S 26-39
fer III Nitrate 7782-61-8
Ferric chloride hexahydrate ----------------
chlorure ferrique FeCl 3 , 6 H2O 10025-77-1 --- Xn R22;R38;R41 S26;S39
Ferrocène / bis cyclopentadienyl 102-54-5 F;Xn;N R11;R22;R51/53
iron 203-039-3 S22;S61
Ferrous ammonium sulfate
hexahydrate / Fer II Sulfate R.P. 7783-85-9 233-151-8 Xi R36/37/38 S26;S37/39
HAuCI4 . 3H2 G4022 cas 16961-25-4 16961-25-4
Gold chloride trihydrate acs reagent code produitO 240-948-4 C R34
Hydrogen peroxyde 7722-84-1 R5 O; R8 - C; R35 - Xn; R20/22 R5 - S1/2 S17 S26 S28 S36/37/39
231-765-0 S45
hydrogen chloride /acide
chlorhydrique H Cl 7647-01-0 231-595-7 C+ R34 - Xi; R37 S1/2 S26 S45
hydrogen chloride /Acide 7664-39-3 T+; R26/27/28 - C; R35 S 7/9-26-36/37 S45
fluorhydrique 231-634-8
iron pentacarbony /fer carbonyle 13463-40-6 236-670-8 F T+ ; Very Toxic
Isopropanol /Propanol-2( alcool 67-63-0 F R11-Xi R36-R67
isopropylique) 200-661-7 S16;S24/25;S26;S7
Lead dinitrate/ Plomb Nitrate 10099-74-8 O;T;N R20/22;R33;R50/53;R61;R62;R8 S17;S45;S53;S60;S61
233-245-9
Mercure 7439-97-6 231-299-8 Repr. Cat. 2; R61 -T+; R26 -T; R48/23-N; S 53 S45 S60 S61
R50-53
méthanol 67-56-1 T ; F; R11;R23/24/25;R39/23/24/25 S16;S36/37;S45;S7
200-659-6
Methylene Blue / Bleu de Xn R22;R41
méthylène 61-73-4 200-515-2 S26;S39
nickel dichloride /Nickel 231-743-0 Carc. Cat. 1; R49 - Muta. Cat. 3; R68 -
chlorure 7718-54-9 Repr. Cat. 2; R61 - T; R23/25-48/23 - Xi; S24;S29;S37;S45;S53;S61
Nickel(II) sulfate / Nickel Carc. Cat. 1; R49 - Muta. Cat. 3; R68 -Repr. S: 2-22-36/37-60-61
sulfate Cat. 2; R61 -T; R48/23 - Xn; R20/22 - Xi; R38
7786-81-4 232-104-9 - R42/43 - N; R50-53
nitric acid _ Acide nitrique 7697-37-2 C R35 S 23-26/37/39-45
231-714-2
Orthoboric acid/ Acide 10043-35-3 233-139-2 S45;S53
orthoborique T R60 Reprotox
orthophosphoric acid /Acide 7664-38-2 C+ R34 S 1/2 S26 S45
orthophosphorique 231-633-2
Oxalic acid dihydrate / Acide 6153-56-6 205-634-3 Xn R21/22 S 24/25
oxalique
perchloric acid / Acide 7601-90-3 231-512-4 O; R8 - C; R35 R5 S 1/2 S23 S26 S36 S45
perchlorique
picric acid / Acide picrique 88-89-1 201-865-9 E; R3- R4-T; R23/24/25
S: 1/2-28-35-37-45
Polethylene (C2H4)n 9002-88-4 ------- ------------ S24/25
Poly(vinyl alcohol) / Alcool
polyninylique 9002-89-5 -------- ------- S24/25
polyéthylène glycol 25322-68-3 25322-68-3 --------- S24/25
Potassium Chloride 7447-40-7
231-211-8 Xi R36 S26;S39
potassium ferricyanide 13746-66-2
/Potassium hexacyanoferrate (III) 237-323-3 R32 S50A
potassium hydrogensulphate 7646-93-7 231-594-1 C; R34 - Xi; R37 S26;S36/37/39;S45
potassium hydroxyde 1310-58-3 215-181-3 R22-35 S26-36/37/39-45
Potassium Nitrite 7758-09-0 O ; T ; N ; R8-25-50 S 45-61
231-832-4
Potassium permanganate 7722-64-7 S2 S60 S61
231-760-3 O; R8 - Xn; R22 - N; R50-53
propanol-1( alcool propylique) 71-23-8 Xi.F R11-41-67 S 7-16-24-26-39
200-746-9
Pyrrole 109-97-7 T R10;R20;R25;R41 S16;S24;S26;S39;S45
Silicium carbure alpha 409-21-2 Xi R36/37/38 S 26 36
206-991-8
Silicon /silice 7440-21-3 231-130-8 F R11 S16;S33;S7/9
Silicon monoxide 10097-28-6 233-232-8 Xi R36/37/38 S26;S36
sodium bicarbonate 144-55-8 205-633-8 --------
sodium borohydride 16940-66-2 F;T R15;R23/24/25;R34 S22;S26;S36/37/39;S43A;S45
sodium Chloride 7647-14-5 ---------------
231-598-3
7789-12-0 O;T+;N
R21;R25;R26;R34;R42/43;R45;R46;R48/23;R
sodium dichromate 234-190-3 50/53;R60;R61;R8 S45;S53;S60;S61
sodium dodecyl sulphate 151-21-3 205-788-1 XN F R10 R20 R21 R22 R36 R37 R38 S26;S36/37/39
sodium hydroxyde 1310-73-2 C R 35 S 26/36/37/39-45
215-185-5
sodium nitrite /nitrite de sodium 7632-00-0 231-555-9 O+ R8 - T+; R25 - N+; R50 S1/2 S45 S61
Sodium thiocyanate 540-72-7 Xn R20/21/22 R32
208-754-4 S: 2-13-61
sodium thiosulphate --------
7772-98-7 231-867-5 S24/25
Sulfuric acid / Acide sulfurique 7664-93-9 231-639-5 C; R35 S26;S30;S45
tetrabutyl titanate/ titanium
(IV)butoxyde 5593-70-4 227-006-8 Xi R36/37/38 S24/25
Tétrahydrofurane 109-99-9 F; R11-19 - Xi; R36/37 S16;S29;S33
tetramethylcyclotetra-siloxane 2370-88-9 219-137-4
thiophene 110-02-1 203-729-4 F;Xn R11;R20/22;R36;R52/53 S16;S36/37/39;S61
toluène CMR 108-88-3 203-625-9 S : -R67
F; R11 - Repr.Cat.3; R63- Xn; R48/20-65 - Xi; R3816-25-29-33
trichloréthylène normal 79-01-6 Carc. Cat. 2; R45 - Muta. Cat. 3; R68 - S 23-36/37-61
R67 - Xi; R36/38 - R52-53
Xylène / Dimethylbenzene 1330-20-7 215-535-7 Xn; R20/21 - Xi; R38 S25
zinc nitrate 7779-88-6 231-943-8 ----
SILICONE
Ethylenediamine silicone oil 47v
2s 107-15-3 203-468-6 C R10;R21/22;R34;R42/43 S23;S26;S36/37/39;S45
diméthyldichlorosilane =silicone
RESINE EPOXY RESOLTECH
1800- PRO bisphénol-A 025068-38-6 500-033-5 Xi N 36/38-43-51/53
bisphénol-F- 028064-14-4 Xi N 36/38-43-51/53
1,6 hexanediolglycidether 016096-31-4 Xi R36/38-43-52/53
RESINE EPOXY RESOLTECH
1083- PRO Méthylènedi(cyclohexylamine) 1761-71-3 C R 22-35-37-43
3,-animométhyl-3,5,5- 2855-13-2 C R 21/22-34-43-52/
triméthylcyclohexylamine R53
RESINE EPOXY RESOLTECH
1025- PRO bisphénol-F- 055492-52-9 Xi N R36/38-43-51/53
C13/C15-Alkylglycidylether 068081-84-5 Xi N r 36/38-43-51/53
4-nonylphénol, ramifié 084852-15-3 C N R22-34-50/53
bisphénol-A 025068-38-6 500-033-5 Xi N R36/38-43-51/53
RESINE EPOXY RESOLTECH
1083- PRO 4,4'-isopropylidenediphénol 000080-05-7 201-245-8 Xi R36/37/38-43
2,2-azapentane-1,5-diamine 000111-40-0 203-865-4 X C R21/22-34-43
2-pipérazine-1-yléthylamine 000140-31-8 205-411-0 C R21/22-34-43-52/
Nonylphénol 025154-52-3 246-672-0 C N R22-34-50/53
Poly(oxy(methyl-1,2-ethanediyl 009046-10-0 C R 34
RESINE EPOXY RESOLTECH
1080- PRO 1,4-bis(2,3-époxypropoxy)butane 2425-79-8 Xn R20/21-36/38-43- 52/53
bisphénol-A 025068-38-6 500-033-5 Xi N R36/38-43-51/53
3-aminomethyl-3,5,5-
EPOLAM 5015 DURCISSEUR trimethylcyclohexylamine 2855-13-2 C; R 21/22-34-43-52/53
Polyoxyalkyleneamine 9046-10-0 C; R 21/22-34
EPOLAM 5015 RESINE bisphenol-F-epichlorhydrine 9003-36-5 Xi, N; R 36/38-43-51/53
bisphenol A-(epichlorhydrin); 25068-38-6 Xi, N; R 36/38-43-51/53
resine polyurethane Mapaero
-
Risk Codes
shown as
Chemical data sheets available in many countries now contain codes for certain "risk phrases", R23, R45 etc. These risk phrase codes have the following meanings:
R1 Explosive when dry. R44 Risk of explosion if heated under confinement.
R2 Risk of explosion by shock, friction, fire or other source of ignition. R45 May cause cancer.
R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition. R46 May cause heritable genetic damage.
R4 Forms very sensitive explosive metallic compounds. R47 May cause birth defects
R5 Heating may cause an explosion. R48 Danger of serious damage to health by prolonged exposure.
R6 Explosive with or without contact with air. R49 May cause cancer by inhalation.
R7 May cause fire. R50 Very toxic to aquatic organisms.
R8 Contact with combustible material may cause fire. R51 Toxic to aquatic organisms.
R9 Explosive when mixed with combustible material. R52 Harmful to aquatic organisms.
R10 Flammable. R53 May cause long-term adverse effects in the aquatic environment.
R11 Highly flammable. R54 Toxic to flora.
R12 Extremely flammable. R55 Toxic to fauna.
R13 Extremely flammable liquefied gas R56 Toxic to soil organisms.
R14 Reacts violently with water. R57 Toxic to bees.
R15 Contact with water liberates extremely flammable gases. R58 May cause long-term adverse effects in the environment.
R16 Explosive when mixed with oxidizing substances. R59 Dangerous to the ozone layer.
R17 Spontaneously flammable in air. R60 May impair fertility.
R18 In use, may form inflammable/explosive vapour-air mixture. R61 May cause harm to the unborn child.
R19 May form explosive peroxides. R62 Risk of impaired fertility.
R20 Harmful by inhalation. R63 Possible risk of harm to the unborn child.
R21 Harmful in contact with skin. R64 May cause harm to breastfed babies.
R22 Harmful if swallowed. R65 Harmful: may cause lung damage if swallowed.
R23 Toxic by inhalation. R66 Repeated exposure may cause skin dryness or cracking.
R24 Toxic in contact with skin. R67 Vapours may cause drowsiness and dizziness.
R25 Toxic if swallowed. R68 Possible risk of irreversible effects.
R26 Very toxic by inhalation. R20/21 : Harmful by inhalation and in contact with skin.
R27 Very toxic in contact with skin. R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed.
R28 Very toxic if swallowed. R20/22 : Harmful by inhalation and if swallowed.
R29 Contact with water liberates toxic gas. R21/22 : Harmful in contact with skin and if swallowed.
R30 Can become highly flammable in use. R23/24/25 : Toxic by inhalation, in contact with skin and if swallowed.
R31 Contact with acids liberates toxic gas. R23/25 : Toxic by inhalation and if swallowed.
R32 Contact with acid liberates very toxic gas. R26/27/28 : Very toxic by inhalation, in contact with skin and if swallowed.
R33 Danger of cumulative effects. R26/28 : Very toxic by inhalation and if swallowed.
R34 Causes burns. R36/37 : Irritating to eyes and respiratory system.
R35 Causes severe burns. R36/37/38 : Irritating to eyes, respiratory system and skin.
R36 Irritating to eyes. R36/38 : Irritating to eyes and skin.
R37 Irritating to respiratory system. R37/38 : Irritating to respiratory system and skin.
R38 Irritating to skin. R42/43 : May cause sensitization by inhalation and skin contact.
R39 Danger of very serious irreversible effects. R48/22 : Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R40 Limited evidence of a carcinogenic effect. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the
R41 Risk of serious damage to the eyes. aquatic environment.
R42 May cause sensitization by inhalation. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
R43 May cause sensitization by skin contact. environment.
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety Description
EC Safety phrases are extensively used in the world, in data sheets of chemicals. The codeshave the following meanings:
S1 Keep locked up. S38 In case of insufficient ventilation, wear suitable respiratory equipment.
S2 Keep out of the reach of children. S39 Wear eye / face protection.
S3 Keep in a cool place. S40 To clean the floor and all objects contaminated by this material, use .... (there follows
S4 Keep away from living quarters. suitable cleaning material).
S5 Keep contents under ... (there follows the name of a liquid). S41 In case of fire and / or explosion do not breathe fumes.
S6 Keep under ... (there follows the name of an inert gas). S42 During fumigation / spraying wear suitable respiratory equipment.
S7 Keep container tightly closed. Safety Description
S8 Keep container dry. S43 In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S9 Keep container in a well-ventilated place. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the
S12 Do not keep the container sealed. label whenever possible.)
S13 Keep away from food, drink and animal foodstuffs. S46 If swallowed, seek medical advice immediately and show this container or label.
S14 Keep away from ... (a list of incompatible materials will follow). S47 Keep at temperature not exceeding...
S15 Keep away from heat. S48 To be kept wet with (there follows a material name).
S16 Keep away from sources of ignition. S49 Keep only in the original container.
S17 Keep away from combustible material. S50 Do not mix with ...
S18 Handle and open container with care. S51 Use only in well ventilated areas.
S20 When using, do not eat or drink. S52 Not recommended for interior use on large surface areas.
S21 When using do not smoke. S53 Avoid exposure - obtain special instructions before use.
S22 Do not breathe dust. S56 Dispose of this material and its container at hazardous or special waste collection point.
S23 Do not breathe vapour. S57 Use appropriate container to avoid environmental contamination.
S24 Avoid contact with skin. S59 Refer to manufacturer / supplier for information on recovery / recycling.
S25 Avoid contact with eyes. S60 This material and its container must be disposed of as hazardous waste.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical S61 Avoid release to the environment. Refer to special instructions / safety data sheets.
advice. S62 If swallowed, do not induce vomitting; seek medical advice immediately and show this
S27 Take off immediately all contaminated clothing. container or label.
S28 After contact with skin, wash immediately with plenty of soap-suds. S1/2 : Keep locked up and out of the reach of children.
S29 Do not empty into drains. S24/25 : Avoid contact with skin and eyes.
S30 Never add water to this product. S36/37 : Wear suitable protective clothing and gloves.
S33 Take precautionary measures against static discharges. S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S35 This material and its container must be disposed of in a safe way. S37/39 : Wear suitable gloves and eye/face protection.
S36 Wear suitable protective clothing.
S37 Wear suitable gloves.