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Developing Organic-Inorganic Interface as a Sensor for Bio-molecules





A consortium under construction is looking for an industrial partner for validating the

new technology rising form the development of an organic-inorganic interface

sensor for bio-molecules.

In this project we aim to develop an integrated system by interfacing an inorganic

based electronic device and organic or biological active layer that will serve as a

platform for detection of specific biological components. Investigation and

development of such interface will create a generic tool for further studies of many

biological systems. It will enable to develop novel commercial systems for detection

and measurements of biological material and processes.

The base for this system is a simple GaAs-based device called Molecular Controlled

SEmiconductor Resistor (MOCSER). Instead of controlling the current through the

device by a metal gate, we propose to adsorb molecules between the source and

drain electrodes. Those molecules will be able to selectively bind bio-molecules, the

analyte. Upon binding the analyte, the electrical potential on the surface of the

MOCSER changes, thus changing its resistance. Hence, a chemical process is

transformed to a change in an electronic signal.

Specifically, we propose to focus on the detection of short single stranded DNA (DNA

oligomers). Short DNA oligomers will be adsorbed on the MOCSER. When exposed to

their complementary strands in solution the adsorbed oligomers will hybridize to form

double strands. The hybridization process will vary the potential on the surface of the

MOCSER, hence result in a change in the current flowing through the device. In

principle the same concept can be used for detecting antibodies and proteins.

There are several advantages to this system over common DNA arrays. The detection

requires no special modification of the DNA strands, since there is no need for an

optical detection system. Conceptually, the measuring of the electrical current

through the device provides better sensitivity than optical detection, thus the device

should be able to detect lower concentration of analyte. The concern of false

positive due to left over strands is not an issue, since only those strands chemically

attached are detected. Finally, construction of high throughput arrays made up of

MOCSER elements is very simple and straightforward and makes the all detection

system significantly less expensive.







Specific research areas will include:

DNA analysis

Synthesis DNA manufacturing

Genomics



Technological challenges

Detecting short strand DNA oligomers with 1 base mismatch with minimal sample

preparation.





Deliverables

The potential deliverables may include:

Comparison of state of the art detection systems to the proposed new method.



Instrument used

Specific Targeted Research Project (STREP)

Call information

FP6-2003-NMP-T1-3-MAIN

3.4.1.2: Nano-biotechnologies – New knowledge on interfaces for new applications



Participants already aquired:



Participant Task

Chiaro Networks Co-ordination, Design, development and manufacturing the

GaAs device, the required test system and liquid transport

system.

Weizmann Institute Development of surface preparation and adsorption

methods. Electrical measurements of the hybrid device. It

will also use the low energy photoelectron spectroscopy to

investigate the electronic properties of substrates covered

with the organic layer.



Centre National de la Studying the vibrational spectra of the substrates and of the

Recherche Scientifique adsorbed layers.

(CNRS)

Centro de Química-Física Studying electronic properties of the substrates and the

Molecular adsorbed layers, using XPS, Auger and high-energy electron

energy loss spectroscopy.



Institute of Moelcular Developing DNA preparation methods. Preparing suitable

Biology and Biophysics, DNA samples from various sources.

Georgian Academy of

Science

School of Biological Preparing DNA substrates and assembly these with matches

Sciences, University of and mismatches determining appropriate DMA sequences

Portsmouth for attachment. Prepare a system using other methods of

detection for comparison.



Partner sought: Validation the new DNA detection technology in an

Industrial company in the industrial environment

bio-chemistry area.

Can be DNA analysis

equipment manufacturer,

analysis services lab,

synthesis DNA manufacturer

or similar.





Time table

Proposal is to be submitted by May 12, 2004

The project duration is 3 years.



Contact person Information:

Amon Schneider

Managing Director

Orshanir Consulting Ltd.



GSM +972-54-658-748

eFax +972-3-548-0075

amon@orshanir.com



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