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					Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
Common Name

Phosphopeptide Elution Buffer II
Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747 Not available. Not available. Not available. Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747

Code MSDS# Validation Date

Supplier

1856122 component of #0029580 1774
8/21/98

Synonym Trade name Material Uses Manufacturer

Print Date

8/21/98

Responsible Name Company
In Case of Emergency

CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616

Section 2. Composition and Information on Ingredients
Name CAS # % by Weight Exposure Limits

1) Phosphopeptide Elution Buffer II

100

Not available.

Section 3. Hazards Identification
Physical State and Appearance Emergency Overview

Liquid. DANGER! HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED. CONTAINS MATERIAL WHICH MAY CAUSE RESPIRATORY TRACT, SKIN, EYES DAMAGE. CAUSES SEVERE SKIN BURNS. Keep away from heat, sparks and flame. Do not ingest. Avoid breathing vapors or spray mists. Do not get on skin or clothing. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Routes of Entry Potential Acute Health Effects

Eyes Not available. Skin Irritation of the product in case of skin contact: Not available. Sensitization of the product: Not available. Hazardous in case of skin contact (corrosive). Skin contact may produce burns. Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Over-exposure by inhalation may cause respiratory irritation. Ingestion May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Potential Chronic Health Effects
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

Medical Conditions Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin Aggravated by Overexposure irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

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Phosphopeptide Elution Buffer II
Overexposure Not available. /Signs/Symptoms See Toxicological Information (section 11)

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Section 4. First Aid Measures
Eye Contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Not available.

Skin Contact

Inhalation Ingestion Notes to Physician

Section 5. Fire Fighting Measures
Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire Hazards Special Remarks on Explosion Hazards

Flammable. The lowest known value is 539°C (1002.2°F) (Formic Acid). The lowest known value is OPEN CUP: 68.89°C (156°F). (Formic Acid) The greatest known range is LOWER: 18% UPPER: 57% (Formic Acid) These products are carbon oxides (CO, CO2). Not available. Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Be sure to use an approved/certified respirator or equivalent. Not available. Not available.

Section 6. Accidental Release Measures
Small Spill and Leak Large Spill and Leak

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Flammable liquid. Corrosive liquid. Keep away from heat Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

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Phosphopeptide Elution Buffer II Section 7. Handling and Storage
Handling

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To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Corrosive materials should be stored in a separate safety storage cabinet or room.

Storage

Section 8. Exposure Controls/Personal Protection
Engineering Controls

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Eyes Face shield. Body Full suit.

Personal Protection

Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Feet Boots.
Protective Clothing (Pictograms)

Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. a Large Spill Product Name
1) Phosphopeptide Elution Buffer II

Exposure Limits
Not available.

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
Physical State and Appearance Molecular Weight Molecular Formula pH (1% Soln/Water) Boiling/Condensation Point Melting/Freezing Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate VOC

Liquid. Not applicable. Not applicable. Acidic.

Odor Taste Color

Not available. Not available. Not available.

The lowest known value is 100.5°C (212.9°F) (Formic Acid). May start to solidify at 8.4°C (47.1°F) based on data for: Formic Acid. Not available. The only known value is 1.21 (Water = 1) (Formic Acid). The highest known value is 35 mm of Hg (@ 20°C) (Formic Acid). The highest known value is 1.6 (Air = 1) (Formic Acid). Not available. Not available. Not available. Not available.

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Phosphopeptide Elution Buffer II
Viscosity LogKow Ionicity (in Water) Dispersion Properties Solubility

Page: 4/6

Not available. Not available. Not available. See solubility in water, methanol. Partially soluble in cold water, hot water, methanol.

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity
Stability and Reactivity Conditions of Instability

The product is stable. Keep away from heat, sparks and flame. (Formic Acid)

Incompatibility with Various Reactive with oxidizing agents, alkalis. Substances Hazardous Decomposition Products Hazardous Polymerization

Not available. Not available.

Section 11. Toxicological Information
Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans

Acute oral toxicity (LD50): 1100 mg/kg [Rat]. (Formic Acid). The substance is toxic to upper respiratory tract, skin, eyes, respiratory tract. Hazardous in case of skin contact (corrosive), of ingestion.

Special Remarks on Toxicity Not available. to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans

Not available. Not available.

Section 12. Ecological Information
Ecotoxicity BOD5 and COD Biodegradable/OECD Mobility

Not available. Not available. Not available. Not available. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation

The products of degradation are less toxic than the product itself. Not available.

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Phosphopeptide Elution Buffer II Section 13. Disposal Considerations
Waste Information Waste Stream

Page: 5/6

Not available. Not available.

Consult your local or regional authorities.

Section 14. Transport Information
DOT Classification

Class 8: Corrosive liquid.

Corrosive liquids n.o.s. (Formic Acid) UN1760 Not available.
Marine Pollutant

Not available.

Hazardous Substances Reportable Quantity Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification

Not available. Not available. Class 8: Corrosive liquid. Class 8: Corrosive liquid. Highly corrosive. Acid. Class 8: Corrosive liquid. Class 8: Corrosive liquid.

Section 15. Regulatory Information
HCS Classification U.S. Federal Regulations

Class: Flammable liquid having a flash point lower than 37.8°C (100°F). Class: Corrosive liquid. TSCA 4(a) proposed test rules: Formic Acid TSCA 8(b) inventory: Formic Acid TSCA 8(d) H and S data reporting: Formic Acid SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. SARA 313 toxic chemical notification and release reporting: Formic Acid: 1% Clean water act (CWA) 307: No products were found. Clean water act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Class E: Corrosive liquid. CEPA DSL: Formic Acid

International Regulations WHMIS (Canada)

EINECS DSCL (EEC)

Not available. R11- Highly flammable. R25- Toxic if swallowed. R35- Causes severe burns.

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Phosphopeptide Elution Buffer II
International Lists State Regulations

Page: 6/6

Australia: Formic Acid Pennsylvania RTK: Formic Acid: (environmental hazard) Minnesota: Formic Acid Massachusetts RTK: Formic Acid New Jersey: Formic Acid California prop. 65: No products were found.

Section 16. Other Information
Label requirements

HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED. CONTAINS MATERIAL WHICH MAY CAUSE RESPIRATORY TRACT, SKIN, EYES DAMAGE. CAUSES SEVERE SKIN BURNS.
Health Fire Hazard Reactivity Personal Protection

Hazardous Material Information System (U.S.A.)

*

3 National Fire 2 Protection 0 Association (U.S.A.)

2
Health

Fire Hazard

3

ACID

0

Reactivity Specific Hazard

References Other Special Considerations

Not available. Not available.
Verified by Company. Printed 8/21/98.

Validated by Company on 8/21/98. CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Notice to Reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.


				
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