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Biochemistry

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INTRODUCTION TO BCH452

Biochemistry 452, 2010



Dennis Brown, PhD

E-mail:

dennis_brown@ncsu.edu

Trino Ascencio-Ibáñez, PhD

E-mail:

trino_ascencio@ncsu.edu

TA for BCH 452





Andy Caldwel: accaldwe@ncsu.edu

E-mail



 Major mechanism of communication

 Notify you of changes in schedule and project

 Send updates on experiment results

 Answer your questions

 Keep your mail box clean

 Lecture notes on web are too large to send

 Some Mails may still push you over quota

Lab Text



BCH 452 “ Introductory Biochemistry”

Author: Charles Hardin & James Knopp.

NCSU

Available at Sir Speedy

 2526 Hillsborough ST

$25.50 (approximate)

Schedule



Lab opens at 1:15

 Turn in Pre lab questions & lab reports

 Collect any handouts

1.30 lecture

2:00 lab exercise

NO MAKE UP LABS

Please be aware of this

BCH 452



Will introduce fundamental techniques in

biochemical analysis

Will teach the principles upon which the

technology depends

Will make you familiar with theory and

practice of the technology

More Importantly BCH 452

 Will stress proper laboratory technique

 Reproducibility

 Understand and eliminate errors

 Will stress proper record keeping and data

reporting

 Necessary for archival considerations

 For intellectual property

 For trouble-shooting

Concept of 452

 Teach techniques in common use in

biochemistry laboratory science

 Try to present situations that exist in a real

laboratory situation

 Move from “exercises” with predictable outcomes.

 To “experiments” with doubtful outcomes

 Important to understand and explain

anomalous results

My Job…



 To be certain that you understand the

principles that the experiments will examine

 To be certain that you understand how the

apparatus employed in the experiment

functions

 To be certain that you understand the reason

for each step in the experimental protocol

Lab Safety (Front of Lab Manual)



 Hazardous reagents

 Volatiles

 Corrosives

 Mutagens

 Safety goggles

 Eyewash, safety showers, fire extinguishers,

sharps containers

 Exits

 NO OPEN TOE SHOES

Model Molecules



Three major classes of biomolecules

 Carbohydrates

 Proteins

 Nucleic acids

Model Techniques



 Spectrophotometry

 Chromatography

 Electrophoresis

 Biochemical fractionation

 PCR and qPCR

 ELISA

Your Responsibility



 Read the experiment before you come to lab

 Read pertaining sections of appendix

 Read “Tips”

 Turn in the pre lab exercise

 Have all required materials

 Some of the protocols can be confusing.

Make a flow sheet that outlines the steps.

Grading

 Lab reports: 130 total points

 Pre Lab Questions: 36 points

 Exams (2): 25 points each

 Total 216 points

 A+216 - 205 C+ 150 - 140

 A 204 - 193 C 139 - 130

 A- 193 - 184 C- 129 - 119

 B+183 - 173 D 118 - 108

 B 172 - 162 F 107 - 0

 B- 161 - 151

Reporting



 Prelab questions

 Due at beginning of designated lab

 Ensures that you have read and understand the exercise

 Completed report

 Due at beginning of next exercise

Laboratory Notebook (Ideal)



 No loose pages

 Generates copies

 All entries dated

 Each page dated

 Pages signed by a witness attesting to date

(extreme)

 Retention time (7 years)

 Will provide extra credit if in good shape

Lab Reports should contain

 Statement of purpose

 Why you are doing the experiment

 What you wish to determine

 Brief account of theory and design of experiment

 Summary or flow chart

 The raw data

 All calculations

 Results

 Conclusions and interpretation

Lab reports are personal



You should write your reports as a

personal effort, even if all the data and

the experiments are performed as a

group.

A form for lab write up in lab

manual

 Title all sections in the manuscript

 Abstract, Discussion, Graph titles, etc.

 Abstract should contain a brief summary of the

experiment

 “I investigated the effect of temperature on the

activity of the enzyme Stickase by monitoring its

ability to convert stick to broken stick. This was

done by determining the accumulation of broken

stick by spectrophotometry (A260) at temperatures

between 10 to 60 degrees C. I found that Stickase

converted stick to broken stick most efficiently at a

temperature of 37oC”

Lab Report (read information in manual)



Record all your experimental data

including changes in protocol

Include your calculations and raw data

as appendix attached to your report.

Label co ordinates. Be careful with units,

spelling and grammar

Explain sources of error

Things that you should know

Units of Biochemistry



Decade system (Metric-decimal system)

 Moles

 Meters

 Liters

 Grams

 Centigrades

Elementary calculations



Gram Molecular Weight

Dilutions (very important in lab

environment)

Rate equations

“What is the molar concentration of a

solution that is 5 millimolar NaCl”

Significant Figures



Determines the value of a data set

Includes estimations

 3.2 is not the same as 3.20 or 3.200

Presentation of Data





Data tables

Graphs

A Table or Graph should:



Be easy to understand

Project a message

Does not require extensive reference to

text

Experiment

 A solution of compound X is reacted with

reagent Y which causes the production of a

light absorbing product. The amount of light

absorbing product indicates how much

compound X is present. The sample

containing X is divided into three aliquots and

the experiment is repeated three times at

three wavelengths.

Lousy Table

Results of the three experiments



Absorbance values Absorbance values Absorbance values

for reaction #1 at for reaction #2 at for reaction #3 at

360, 420 and 540 360, 420 and 540 360, 420 and 540

nm nm nm





0.875 (360) 0.885 (360) 0.823 (360)



0.253 (420) 0.250 (420) 0.244 (420)



0.164 (540) 0.165 (540) 0.157 (540)

Good Table



Absorbance values for the “experiments” at 360,420 and

540 nm

Trial # A360 A420 A540



1 0.876 0.253 0.164



2 0.885 0.250 0.163



3 0.825 0.244 0.157

Bar Graph A: Compares Values at each

wavelength, Shows Reproducibility





0.9

0.8

0.7

0.6

0.5

Absorbance Trial 1

0.4

0.3 Trial 2

0.2 Trial 3

0.1

0

A360 A420 A540

Wavelength

Bar Graph B: Compares absorbance at different

wavelength, shows sensitivity





0.9

0.8

0.7

0.6

0.5 A360

Absorbance A420

0.4

0.3 A540

0.2

0.1

0

Trial 1 Trial 2 Trial 3

Next Exercise (January 25th, 26th,

27th)

Carbohydrates

 Section A1 in lab manual

 Read carefully prior to coming to lab.

 Do the pre lab questions and turn them in

at your arrival.

If you don’t know how to use a

micropipette:

Stay today to get trained, this task is

extremely important for the good

practice of Biochemistry and therefore,

your grade in BCH452.



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