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					References:

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22. Chen, D.; Klankermayer Metal-free catalytic hydrogenation of imines with
    tris(perfluorophenyl)borane. J. Chem. Commun. 2008, 2130–2131.
23. Axenov, K.V.; Kehr, G.; Frolich, R.; Erker, G. Catalytic Hydrogenation of
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24. Sumerin, V.; Schulz, F.; Nieger, M.; Leskela, M.; Repo, T.; Reiger, B.
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Additional references:

   1. Spies, P.; Schwendemann, S.; Lange, S.; Kehr, G.; Frolich, R.; Erker, G.
       Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated
       Phosphinoalkenylboranes. Angew. Chem. Int. Ed. 2008, 47, 7543–7546.
   2. Spies, P.; Erker, G.; Kehr, G.; Bergander, K.; Frolich, R.; Grimme, S.;
       Stephan, D.W. Rapid intramolecular heterolytic dihydrogen activation by a
       four- membered heterocyclic phosphane–borane adduct. Chem. Commun.
       2007, 5072–5074.
   3. Chase, P.A.; Jurca, T.; Stephan, D.W. Lewis acid-catalyzed
       hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2.
       Chem. Commun. 2008, 1701–1703.
   4. Jiang, C.; Blacque, O.; Berke, H. Metal-free hydrogen activation and
       hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthalene.
       Chem. Commun. 2009, 5518–5520.
   5. Geier, S.J.; Gille, A.L.; Gilbert, T.M.; Stephan, D.W. From Classical
       Adducts to Frustrated Lewis Pairs: Steric Effects in the Interactions of
       Pyridines and B(C6F5)3. Inorg. Chem. 2009, 48, 10466–10474.
   6. Lu, G.; Li, H.; Huang, F.; Wang, Z.X. Computationally Designed Metal-
       Free Hydrogen Activation Site: Reaching the Reactivity of Metal-Ligand
       Bifunctional Hydrogenation Catalysts. Inorg. Chem. 2010, 49, 295–301.
   7. Welch, G.C.; Stephan, D.W. Facile Heterolytic Cleavage of Dihydrogen by
       Phosphines and Boranes. J. Am. Chem. Soc. 2007, 129, 1880–1881.
   8. Chase, P.A.; Welch, G.C.; Jurca, T.; Stephan, D.W.; Metal-Free Catalytic
       Hydrogenation. Angew. Chem. Int. Ed. 2007, 46, 8050–8053.
   9. Rokob, T.A.; Hamza, A.; Papai, I. Rationalizing the Reactivity of
       Frustrated Lewis Pairs: Thermodynamics of H2 Activation and the Role of
       Acid-Base Properties. J. Am. Chem. Soc. 2009, 131, 10701–10710.
   10. Momming, C.M.; Fromel, S.; Kehr, G.; Frolich, R.; Grimme, S.; Erker, S.
       Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated
       Substrates: Evidence for a Concerted Olefin Addition Reaction. J. Am.
       Chem. Soc. 2009, 131, 12280–12289.
   11. Doring, S.; Erker, G.; Frolich, R.; Meyer, O.; Bergander, K. Reaction of
       the Lewis Acid Tris(pentafluorophenyl)borane with a Phosphorus Ylide:
       Competition between Adduct Formation and Electrophilic and Nucleophilic
       Aromatic Substitution Pathways. Organometallics 1998, 17, 2183–2187.


Relevant reviews:

   1. Stephan, D.W.; Erker, G. Frustrated Lewis Pairs: Metal-free Hydrogen
      Activation and More. Angew. Chem. Int. Ed. 2010, 49, 46-76.
   2. Stephan, D.W. Frustrated Lewis pairs: a new strategy to small molecule
      activation and hydrogenation catalysis. J. Chem. Soc. Dalton Trans. 2009,
      3129–3136.
3. Stephan, D.W. “Frustrated Lewis pairs”: a concept for new reactivity and
   catalysis. Org. Biomol. Chem. 2008, 6, 1535–1539.
4. Sumerin, V.; Schulz, F.; Nieger, M.; Wang, C.; Atsumi, M.; Leskela, M.;
   Pyykko, P.; Repo, T.; Reiger, B. Experimental and theoretical treatment of
   hydrogen splitting and storage in boron–nitrogen systems. J. Organomet.
   Chem. 2009, 694, 2654–2660.
5. Denmark, S.E.; Beutner, G.L. Lewis Base Catalysis in Organic Synthesis.
   Angew. Chem. Int. Ed. 2008, 47, 1560–1638.
6. Paull, D.H.; Abraham, C.J.; Scerba, M.T.; Alden-Danforth, E.; Lectka, T.
   Bifunctional Asymmetric Catalysis: Cooperative Lewis Acid/Base Systems.
   Acc. Chem. Res. 2008, 41, 655–663.

				
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