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					Data sheet on product safety
EVP PPS037 e, December 2007 supersedes edition of November 27, 2005 (unnumbered)

page 1 of 3

®

= registered trademark of BASF Group, unless noted otherwise

Sicopal Yellow L 1120
14059-33-7 237-898-0 bismuth vanadate, BiVO4 Pigment Yellow 184 / 771740 Sicopal® Yellow L 1120 consists of fine granules of bismuth vanadate with a stabilizer coat consisting of zinc and aluminum compounds. In animal studies, Sicopal® Yellow L 1120 did not display acute toxicity. No acute irritant effect was shown in tests to determine the acute irritation of skin and mucous membranes. Animal studies gave some indication to inhalational toxicity. Changes in lung weight and lung tissue were found in rats exposed to high concentrations of dust. Toxic effects can be observed only when the concentration in the lungs exceeds a certain level that usually does not occur under the usual conditions of industrial hygiene and, in particular, when processing low-dusting products. In experiments on animals, bismuth vanadate pigments did not display sensitizing effects. Bismuth compounds are not known to have caused damage to the environment and they are not expected to. Vanadium compounds except vanadium pentoxide have toxic effects on humans, animals and plants only at relatively high concentrations. Vanadium is an essential trace element for humans and animals. In experiments on the ecotoxicity on fish and bacteria, bismuth vanadate pigments did not display toxic effects. Due to their insolubility in water, dissolved heavy metals are not expected to be given off to the seepage water of a controlled dumpsite. WGK 1, low hazard to waters (VwVwS of July 27, 2005, annex 4) (Germany) Labeling according to the German Ordinance on dangerous substances or corresponding EU directives: no labeling required due to a particulate matter fraction of < 0.1 % When Sicopal® Yellow L 1120 is ground to powder, this labeling is required:

®

CAS number EINECS number Description Colour Index Chemical nature

Toxicology

Ecology

Water hazard classification

Labeling

EVP PPS037 e, December 2007

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Sicopal® Yellow L 1120

Xn R48/20

harmful danger of serious damage to health by prolonged exposure, harmful by inhalation

Dangerous goods classification Heavy metal contents

not hazardous under transport regulation No compounds of lead, cadmium, hexavalent chromium or mercury have intentionally been added to Sicopal® Yellow L 1120. Analyses of representative standard samples have shown that the sum of the total content of these elements is less than 100 mg/kg and thus below the limits laid down in the EU packaging directive 94/62/EC and the American CONEG model. The requirements of the EU directive on electronic devices, 2002/95/EC, and the EU directive on end-of-life vehicles, 2000/53/EC, are met. On average, the total contents of technically unavoidable impurities are as follows: antimony arsenic cadmium chromium cobalt < 5 mg/kg < 3 mg/kg < 10 mg/kg < 20 mg/kg < 20 mg/kg copper lead nickel mercury selenium < 20 mg/kg 20 mg/kg < 20 mg/kg < 1 mg/kg < 1 mg/kg

On average, Sicopal® Yellow L 1120 contains 58 % of bismuth, 14 % of vanadate and 2 % of zinc. Halogen content TA-Luft MAK value By recipe, Sicopal® Yellow L 1120 does not contain halogens. para 3.1.4 – class III (vanadium) (Germany) orientation value, alveolar-passing dust fraction: 0.1 mg/m³ (Germany) According to tests on standard samples, Sicopal® Yellow L 1120 meets the purity requirements of the following food legislations (Type 8081) (also see Heavy metal contents): Europe Germany Italy Spain France USA Resolution AP (89) I BfR Recommendation IX, 190th information of June 1, 1994 Decreto Ministeriale of March 21, 1973 Resolucion del April 11, 1982 de la Subsecretaria de Sanidad not listed in the French positive list (Brochure No. 1227) not listed in the FDA positive list (21 CFR, § 178. 3297).

Food legislation

Children’s toys

Sicopal® Yellow L 1120 meets the purity requirements of the European standard on children’s toys, EN 71, part 3 (Type 8082). Sicopal® Yellow L 1120 is listed in the chemical inventories of the following countries:

Registration status

EVP PPS037 e, December 2007

page 3 of 3

Sicopal® Yellow L 1120

Australia China EU Japan listed Other legislation on chemicals

AICS IECSC EINECS METI

Canada Korea Philippines USA not listed

DSL ECL PICCS TSCA

Sicopal® Yellow L 1120 does not fall under the provisions of the Agreement on Chemical Weapons and does not contain any substances that are mentioned in the German Ordinance on the Prohibition of Certain Chemicals (ChemVerbotsV). It is produced without using substances that destroy ozone (Montreal Protocol on Ozone Depleting Substances).

Please refer to out material safety data sheets and Technical Information bulletins for more information. The Product Safety team of Performance Chemicals for Coatings, Plastics & Specialties Europe will gladly respond to your queries and can be reached at: BASF Aktiengesellschaft E-EVP/QS – J 550 67056 Ludwigshafen, Germany Dr. (Mr.) Raulfs Dr. (Ms.) Gebhardt Tel. Tel. Fax +49 (0)621 60-52650 +49 (0)621 60-72737 +49 (0)621 60-40673

Safety When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed. Note The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. It is the responsibility of the recipient of our products to ensure that any proprietary rights and existing laws and legislation are observed.

20071205_evpps037_e_l_psds_sicopal_1120.doc / EVP PPS037-0712 E

BASF Aktiengesellschaft Performance Chemicals for Coatings, Plastics & Specialties Europe 67056 Ludwigshafen, Germany www.basf.com/pigments www.basf.com/resins www.basf.com/lightstabilizers


				
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